RHEOLOGICAL CONSTANTS MEASUREMENT OF CEMENT PASTE AND CEMENT PASTE FLOW ANALYSIS BY MARKER PARTICLE VISCO-PLASTIC FINITE ELEMENT METHOD

Decalcification shrinkage of cement paste

Decalcification of cement paste in concrete is associated with several modes of chemical degradation including leaching, carbonation and sulfate attack. The primary aim of the current study was to investigate the effects of decalcification under saturated conditions on the dimensional stability of cement paste. Thin (0.8 mm) specimens of tricalcium silicate (C3S) paste, white portland cement (W...

Determining the water - cement ratio , cement content , water content and degree 1 of hydration of hardened cement paste : Method development and validation on 2 paste samples

7 We propose a new method to estimate the initial cement content, water content and free water/cement ratio (w/c) 8 of hardened cement-based materials made with Portland cements that have unknown mixture proportions and 9 degree of hydration. This method first quantifies the composition of the hardened cement paste, i.e. the 10 volumetric fractions of capillary pores, hydration products and unr...

Onset of cohesion in cement paste.

It is generally agreed that the cohesion of cement paste occurs through the formation of a network of nanoparticles of a calcium-silicate-hydrate ("C-S-H"). However, the mechanism by which these particles develop this cohesion has not been established. Here we propose a dielectric continuum model which includes all ionic interactions within a dispersion of C-S-H particles. It takes into account...

Drying Shrinkage Mechanisms in Portland Cement Paste

The shrinkage mechanisms of portland cement paste were investigated from shrinkage, weight loss, and pore structure measurements using nitrogen sorption and mercury intrusion porosimetry (MIP). Thin samples (2.3 mm) of well-hydrated (165 d) pastes of 0.4 and 0.6 water-to-cement (W/C) ratios were dried directly from saturated surface dry state to 75%, SO%, 11%, and 0% relative humidity (rh). Fro...

Image analysis of cement paste: relation to diffusion transport